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Jess Day (Zooey Deschanel) #NewGirl

Who Are the Most Fashionable TV Characters?: Betty Draper (January Jones), Mad Men

Alexis Carrington (Joan Collins) #Dynasty

Who Are the Most Fashionable TV Characters?: Betty Draper (January Jones), Mad Men

Probably the start of the big hair/big ballgown look of the Alexis Carrington "Dynasty" (Joan Collins)

Barney Stinson (Neil Patrick Harris) #HIMYM

Who Are the Most Fashionable TV Characters?: Betty Draper (January Jones), Mad Men

Barney Stinson (Neil Patrick Harris) He's pretty. I managed to watch eight season of How I Met Your Mother in two weeks because of him.

Blair Waldorf (Leighton Meester) #GossipGirl

Who Are the Most Fashionable TV Characters?: Betty Draper (January Jones), Mad Men

Nucky Thompson (Steve Buscemi)   #BoardwalkEmpire

Enoch Malachi "Nucky" Thompson is a fictional character and the protagonist of the HBO TV series Boardwalk Empire. Played by Steve Buscemi, Nucky is based on former Atlantic City political figure Enoch L.

Juliette Barnes (Hayden Panettiere) #Nashville

Nashville Fashion Credits: What the Stars Wore - Season Episode Temperley Top and Metallic Leather Jeans

Carrie Bradshaw (Sarah Jessica Parker)  #SATC

Who Are the Most Fashionable TV Characters?: Betty Draper (January Jones), Mad Men

The 36 Most Memorable Carrie Bradshaw Outfits On 'Sex And The City' Ranked In Order Of Fabulousness

Lady Mary Crawley (Michelle Dockery) #DowntonAbbey

Lady Mary Crawley (Michelle Dockery) always obsessed with her style

Jenna Maroney (Jane Krakowski) #30Rock

Jenna Maroney quote- "I'm not the one who forgot our one minute anniversary!" Ok but I actually loveee this dress.